@InProceedings{FalcãoWaTaVaCoTr:2019:PrDiCa,
author = "Falc{\~a}o, R. and Wachesk, C. and Taiariol, Thalita Sani and
Vasconcelos, G. and Corat, Evaldo Jos{\'e} and Trava-Airoldi,
Vladimir Jesus",
affiliation = "{Universidade Federal de S{\~a}o Paulo (UNIFESP)} and
{Universidade Federal de S{\~a}o Paulo (UNIFESP)} and {Instituto
Nacional de Pesquisas Espaciais (INPE)} and {Instituto de Estudos
Avan{\c{c}}ados (IEAv)} and {Instituto Nacional de Pesquisas
Espaciais (INPE)} and {Instituto Nacional de Pesquisas Espaciais
(INPE)}",
title = "Properties of diamond-like carbon films with incorporated
CVDdiamond nanoparticles",
year = "2019",
organization = "International Conference on Metallurgical Coatings and Thin Films
(ICMCTF), 46.",
abstract = "Diamond-like carbon (DLC) films have been extensively applied as a
surface coating due their attractive mechanical, chemical and
tribological properties. The properties of the a-C:H films can be
significantly enhanced by the presence of diamond nanoparticles in
their structure with some apparent advantages by combining
hardness, low roughness, coefficient of friction,
biocompatibility, etc., of both materials. However,
functionalization of diamond nanoparticles and their severe big
clusters formations represent some challenges to be overcome.
Therefore, the innovative aspect of this work is the growth of DLC
films with incorporated CVD nanodiamonds (NDs), obtained by high
energy ball milling technique with controlled sizes and
functionalization avoiding a lot of clusters formation. In this
work, CVD NDs, obtained at the first time, were chemically
processed due to the high levels of contamination by using fluoric
and nitric acid chemical attack. The DLC films were deposited on a
metallic substrate by using a modified Pulsed DC Plasma-Enhanced
Chemical Vapor Deposition (PECVD) technique, and the incorporation
of the NDs into the DLC films structure was carried using a
colloidal solution of NDs and DLC films precursor. The influence
of the CVD NDs size on physical and chemical properties of the
hybrid film, such as hardness, coefficient of friction,
morphology, and chemical inertia were investigated. Nanoparticles
size and the level of purity was analyzed by dynamic light
scattering and X-Ray diffractometry (XRD) technique, respectively.
The hybrid DLC films were characterized by scanning electronic
microscopy-field emission gun, XRD and Raman scattering
spectroscopy. Also, the qualitative adhesion of the film was
analyzed by RHC 1500 N indentations in accordance with the VDI3198
standard. An apparent application with preliminary results is also
a part of this work.",
conference-location = "San Diego, CA",
conference-year = "19-24 May",
language = "en",
urlaccessdate = "30 abr. 2024"
}